XEROX Material Safety Data Sheet MSDS No: A-1007 Date: 5/27/03 Revision: 9/30/03 Supplier: Xerox Corporation Telephone # (s): Safety Information: (800) 828-6571 Rochester, NY 14644 Health Emergency: (585) 422-2177 Transportation Emergency (Chemtrec): (800) 424-9300 Section I - Product Identification Trade Names/Synonyms: Phaser 3115/3120/3130/WorkCentre PE16 Toner Part No.: 109R639, 109R725, 113R667 WHMIS Status: This is not a WHMIS controlled product. Ingredients (% by wt.) CAS No. Polyester resin (70-80 %) Confidential1 Grafted polyester styrene/acrylate resin (10-20%) Proprietary Carbon black (3-5%) 1333-86-4 Blue pigment (<1) 147-14-8 Section II - Emergency and First Aid Primary Route of Entry: Symptoms of Overexposure: Inhalation Minimal respiratory tract irritation may occur as with Eyes: exposure to large amounts of any non-toxic dust. Flush with water. Skin: Medical Conditions Generally Aggravated by Exposure: Wash with soap and water. None when used as described by product literature. Inhalation: Remove from exposure. Additional Information: Ingestion: None. Dilute stomach contents with several glasses of milk or water. Section III - Toxicology and Health Information The toxicity data noted below is based on the test results of this toner or similar reprographic materials: TLV: 10 mg/m3 (total dust) Oral LD50: >5 g/kg (rats) practically non-toxic. 5 mg/m3 (respirable dust) Dermal LD50: >5 g/kg (rabbits) practically non-toxic. PEL: 15 mg/m3 (total dust) Inhalation LC50: >5 mg/l (rats, 4 hr exposure)practically non-toxic. 5 mg/m3 (respirable dust) >20 mg/l (calculated 1 hr exposure) non-poisonous, DOT. STEL: Not established Eye Irritation: Not an irritant Ceiling: Not established Skin Sensitization: Not a sensitizer. XEL2: 2.5 mg/m3 (total dust) Skin Irritation: Not an irritant 0.4 mg/m3 (respirable dust) Human Patch: Non-irritating, non-sensitizing Mutagenicity: No mutagenicity detected in Ames assay. Carcinogens: None present Aquatic LC50: >1000 mg/l (fathead minnows) non-toxic. Additional Information: The results obtained from a Xerox sponsored Chronic Toner Inhalation Study demonstrated no lung change in rats for the lowest (1mg/m3) exposure level (the level most relevant to potential human exposure). A very slight degree of fibrosis was noted in 25% of the animals at the middle (4mg/m3) exposure level, while a slight degree of fibrosis was noted in all the animals at the highest (16 mg/m3) exposure level. These findings are attributed to "lung overloading", a generic response to excessive amounts of any dust retained in the lungs for a prolonged period. This study was conducted using a special test toner to comply with EPA testing protocol. The test toner was ten times more respirable than commercially available Xerox toner, and would not be 1functNew Jerionalsey lTy rade suitSecrablet for RegistrXerox ation Numequibpmer : ent80100252-. 5001P. 2XEL-Xerox Exposure Limit XEROX Trade Name: Phaser 3115/3120/3130/ WorkCentre PE16 Toner MSDS No.: A-1007 Section IV - Physical Data Appearance/Odor: Fine powder (black, green, blue, red, Yellow or other colors) / faint odor Softening Range: 120°F - 140°F Boiling Point: Not applicable Melting Point: N.D. Solubility in Water: Negligible Specific Gravity (H2O=1): ~1 Evaporation Rate: Not applicable Vapor Pressure (mm Hg): Not applicable Vapor Density (Air=1): Not applicable pH: Not applicable Volatile: Not applicable % (Wt.) Not applicable % (Vol.) Section V - Fire and Explosion Data Flash Point (Method Used): Not applicable Flammable Limits: LEL: Not applicable, UEL: Not applicable NFPA 704: Consumer Use and Storage (“Cartridge” / “Bottle”) -- Health - 0, Fire -1, Reactivity – 0 Manufacturing Use and Storage (“Bulk Containers”) -- Health - 0, Fire -3, Reactivity - 0 Extinguishing Media: Avoid direct stream -- gently apply water mist, water fog, or foam Special Fire Fighting Procedures: Avoid inhalation of smoke. Wear protective clothing and self-contained breathing apparatus. Fire and Explosion Hazards: Toner is a combustible powder. Like most organic materials in powder form, it can form explosive mixtures when dispersed in air. Section VI -Reactivity Data Stability: Stable Hazardous Polymerization: Will Not Occur Hazardous Decomposition Products: Products of combustion may be toxic. Avoid breathing smoke. Incompatibility (Materials to Avoid): None known Section VII - Special Protection Information Respiratory Protection: None required when used as intended in Xerox equipment. Eye Protection: None required when used as intended in Xerox equipment. Protective Gloves: None required when used as intended in Xerox equipment. Other: For use other than normal customer - operating procedures (such as in bulk toner processing facilities), goggles and respirators may be required. For more information, contact Xerox. Section VIII - Special Precautions Handling and Storage: Keep container tightly closed. Conditions to Avoid: Avoid prolonged inhalation of excessive dust. Section IX- Spill, Leak, and Disposal Procedures For Spills or Leakage: Sweep up or vacuum spilled toner and carefully transfer into sealable waste container. Sweep slowly to minimize generation of dust during clean up. If a vacuum is used, the motor must be rated as dust tight. A conductive hose bonded to the machine should be used to reduce static buildup (See Section V). Residue can be removed with soap and cold water. Garments may be washed or dry-cleaned, after removal of loose toner. Waste Disposal Method: This material is not a hazardous waste according to Federal Regulation 40 CFR 261 when disposed. State and Local requirements may, however, be more restrictive. Consult with the appropriate State and Local waste disposal authorities for additional information. Incinerate only in a closed container. Section X - Transportation Information This product is not regulated as a hazardous material